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Le Chatelier's principle in practice

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Hi everyone! party

In this post I won't show you computer related things devil , but one of the most important science: chemistry. I'm afraid I must stress that I like (very much) of science, so the next posts we'll discuss other areas of knowledge like physics, mathematics, biology, and so on.

There is a principle called Le Chatelier's Principle. Basically in chemistry, the principle is used to manipulate the outcomes of reversible reactions, often to increase the yield of reactions. In pharmacology, the binding of ligands to the receptor may shift the equilibrium according to Le Chatelier's principle thereby explaining the diverse phenomena of receptor activation and desensitization. In economics, the principle has been generalized to help explain the price equilibrium of efficient economic systems. In simultan equilibrium systems, phenomena could occur, which are in apparent contradiction to Le Chatelier's principle; these can be resolved by the theory of Response reactions.... but it doesn't matter in this text zip

Here, an example, that was put in FUVEST exam (2002). The FUVEST is considered the most competitive vestibular, and one of the most demanding. It applies for candidates willing to study at University of Sao Paulo (USP) in Brazil:

Bellow, the text of the question:

The Chickens don't perspire and in the summer the frequency of your breathing increases to chill your body. The main elimination of carbon dioxide, through your breathing, makes that your eggshells that is made, principally, of calcium carbonate becomes thinner. To understanding this phenomena, you have to consider this chemical equilibrium.



The question is: In the summer, to the chicken's eggshells doesn't look thinner, it have to eat:

a) water + NaCl (salt)
b)Ration with less calcium
c)water + CO2
d)water + vinegar (RCOOH)
e)atmosphere containing CO2

Answer: Look, it's very interesting. We have to see the fourth equation. If we have more CO2, then the balance will shift to left (Le Chatelier Principle). It will increase the amount of H2CO3. Now, look the third equation: As we see, we have much more H2CO2 than HCO3, then the balance will shift to left. Repeating this steps at equation II and I, we got the answer, that is "c". If you don't understanding, in the end (equation I), the balance is shifted to right (increase CaCO3 = eggshell).

See you in the next post! spock

bye bye

--
Emanuel Valente a.k.a epaduel
http://facebook.com/epaduel
http://twitter.com/epaduel

Resuming error downloads

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First of all, this method also works on megaupload/rapidshare sites like. bigsmile

Of course the browsers are not perfect. This rule applies to the opera browser too awww .

There are cases that we're downloading a (big) file and suddenly the connection stops or the browser freezes. Here I posted an example. I was downloading a file (154MB - Numb3rs series episode) when an error occurred.



As you see, the opera browser has the correct url for the remote file ("From" field). Then we have to copy this address. To resume the download we need the wget program. If you use a linux distribution you probably has it. If no, relax, install it typing (as root) apt-get install wget. Windows users can get wget at http://www.christopherlewis.com/WGet/wget-1.11.4b.zip and save wget.exe in C:\Windows\System32 directory.

Now, we need to run wget in the same place (directory) the file (partially downloaded) with the following arguments: wget -c url. Windows users have first to enter at the prompt (start/run and type "cmd").



Voilà ... the download will be resumed. Other interesting argument is "--limit-rate=RATE" that limit download rate to RATE. Example: wget -c --limit-rate=10k http://url




Sorry for the small screenshots doh doh

It's all folks!

bye bye

Emanuel Valente a.k.a Epaduel

Amsn talking to Opera ! Yes, it's possible

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I have tried to use qt based clients for chatting through msn protocol like kopete. The reason was I want keep my beautiful desktop (i.e do not load gtk apps bigsmile ). A word of warning: I'll write this with all due respect the kopete project.

Well, the Kopete is good, but ... it haven't the same "magics" from amsn. To use amsn, we have to pay something. The price is big amount memory that will be consumed by "wish" application (interpreter used by amsn).

Some people doesn't integrate amsn with your window manager like browser that will open an url, file manager, how it open a file, etc. I'll explain how it's easy doh !

With your amsn opened:
Click "Account"/"Preferences"
Select "Others" Tab.
Fill the form conform to the image below.



Browser: "opera $url"
File Manager: "dolphin $location" (it works if you use kde)
Open File Command: "kfmclient openURL $file

Likewise, if you've other WM, you have to fill the form conform your applications in your hands.

All the best spock

bye
--
Emanuel Valente

Bypassing lan houses

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hi friends..

Today, we going to learn how to bypassing computers from lan houses. It's normal when someone wanna record some files on external media (ex: pendrives) and the network admiministrator blocked this feature ... or... if you wanna run some blocked program.

Here we go... pirate



This method works on following browsers: opera, firefox (all netscape's based), chrome?. The secret is: we going to use the file navigator from these browsers ... aka "file://" command. All we need is to type, for example, "file://C:" in the address bar. As you see... it's very simple, and works! Then, we need navigate until the windows/system32 directory and... click at "cmd.exe". We got a prompt, with it we can copy, move any file for the other media. Try to run blocked programs, some of them are stored at C:/Program Files/.

It's not all, we've the taskkill, that kill a Windows process from the command line. If you've only U$0.50 and if you want waste all your time surfing on internet then you have to use the taskkill command.

Here, an example:

- open the prompt (cmd.exe) as you see before.
- type: "tasklist" it'll list all running process of your pc.
- find the lanhouse manager's PID.
- type: "taskkill /PID 827" (PID = 867) or type: "taskkill /F /PID 827" (/F forces to kill application)

Now, your pc doesn't will have any manager. Enjoy it!

it's all!

See you ! spock

bye bye

--
Emanuel Valente

Tradutor - A QT based project

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hi guys...

When I've anything to do, I become a programmer bigsmile . I used to program in Qt language, that is a cross-platform language, so with the same source code I can compile binaries in different operating systems like windows, mac os, linux, simbian os (nokia cellphones) and others embedded systems. Here, some applications built using Qt:

- Opera Browser, do you know? p
- Adobe Photoshop Album, an image organizing application
- Google Earth, a 3D map program
- Skype, a P2P VOIP application
- KDE, a popular desktop environment for Unix-like operating systems
- Amarok, K3b, KDevelop and KOffice
- Mathematica, Linux and Windows versions use Qt for the GUI front-end

My little application uses the google infrastructure for translate words. It connects to the server (google) like a browser, using the GET method, and gets the translated string (yes, it's very simply). Below, a screenshot:




Link to download: windows .exe + source code http://files.myopera.com/epaduel/projects/tradutor/tradutor-0.9a.rar
Link to download: only source code http://files.myopera.com/epaduel/projects/tradutor/tradutor.tar.gz

It's all folks! Any doubt ... mail-me !

--
Emanuel Valente spock

Hi there ...

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Hello everybody !

I liked the opera service and I'll use for testing....

see you guys ! cheers
February 2012
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